Kirchhoff's Second Law, known as Kirchhoff's Loop Rule, regards the sum of potential differences around a loop in a closed circuit. When used in tandem with Kirchhoff's Junction Rule, it becomes a powerful tool for analyzing complex circuits and finding unknown quantities such as potential differences, resistances, and currents.
Kirchhoff's Loop rule can be seen as a consequence of the conservation of energy. As most parallel circuits contain multiple loops, there is a freedom to choose the simplest loop to apply Kirchhoff's Loop Rule, which often drastically simplifies problems. To apply the loop rule, we consider batteries as sources of positive potential difference, whilst components, such as resistors, are sources of negative potential difference. Let's take a look at an example problem where we can apply both rules to find missing quantities.
Fig. 6 - Applying both of Kirchoff's laws is required to solve the above circuit.
In this example, we're going to look at a somewhat complex circuit, containing resistors and a capacitor in parallel. Here, the capacitor is at steady-state, meaning no current is flowing through it. There is however a build up of charge \(Q\) on the capacitor given by \[Q=CV,\]
where \(C=5\times10^{-9}\,\mathrm{F}\) is the capacitance and \(V\) is the voltage which we do not know yet.
We can apply both of Kirchhoff's Laws to find the missing potential differences and currents in the circuit above, also allowing us to find the charge on the capacitor.
Firstly, Kirchhoff's Junction rule tells us that the currents \(I_1\) and \(I_2\) entering and the current \(I_3\) leaving the junction on the right must satisfy\[\begin{align}I_1+I_2-I_3&=0\,\mathrm{A},\\\implies I_1+I_2&=I_3.\end{align}\]
The left junction is simply the same case, with the signs of the currents reversed, leading to an equivalent equation.
Kirchhoff's Loop Rule gives us two further conditions, from which we can solve all the unknown variables. We can choose a few different loops, but the simplest option is to split the circuit into two main loops, top and bottom, both bypassing the capacitor. We know that the sum of the potential differences around each loop must be zero, giving the following equations.\[\begin{align}5\,\mathrm{V}-V_1-V_2&=0\,\mathrm{V},\\3\,\mathrm{V}-V_2-V_3&=0\,\mathrm{V}.\end{align}\]
We can express the unknown potential differences in terms of the currents and resistances of the resistors using \(V=IR\), which, when combined with equations from Kirchhoff's Junction Rule, forms a set of solvable simultaneous equations.
\[\begin{align}&I_1+I_2=I_3\tag{1},\\&5\,\mathrm{V}-(3\,\mathrm{\Omega})I_1-(1\,\mathrm{\Omega})I_3=0\,\mathrm{V}\tag{2},\\&3\,\mathrm{V}-(1\,\mathrm{\Omega})I_3-(4\,\mathrm{\Omega})I_2=0\,\mathrm{V}\tag{3}.\end{align}\]
If we divide the last two equations by the unit \(\Omega\), we get three current equations:
\[\begin{align}&I_1+I_2=I_3\tag{1},\\&5\,\mathrm{A}-3I_1-I_3=0\,\mathrm{A}\tag{2},\\&3\,\mathrm{A}-I_3-4I_2=0\,\mathrm{A}\tag{3}.\end{align}\]
Substituting \(I_3\) as given in the first equation into the other two equations gives\[\begin{align}&5\,\mathrm{A}-4I_1-I_2=0\,\mathrm{A}\tag{4},\\&3\,\mathrm{A}-I_1-5I_2=0\,\mathrm{A}\tag{5}.\end{align}\]
We can isolate \(I_2\) by combining \((4)\) and \((5)\) in the following way\[\begin{align}(4)-4\times (5)&\implies -7\,\mathrm{A}+19I_2=0\,\mathrm{A},\\&\implies I_2=0.4\,\mathrm{A}.\end{align}\]Substituting this into \((4)\) gives\[\begin{align}I_1=1.2\,\mathrm{A}.\end{align}\]
Putting all together into equation \((1)\) gives all three currents to be\[I_1=1.2\,\mathrm{A},\, I_2=0.4\,\mathrm{A},\, I_3=1.5\,\mathrm{A}.\]
Using \(V=IR\), we find the three voltages to be\[V_1=3.5\,\mathrm{V},\,V_2=1.5\,\mathrm{V},\,V_3=1.5\,\mathrm{V}.\]
Lastly, we want to find the charge on the capacitor. To do so, we need to find the potential difference across the capacitor. Again, Kirchhoff's Loop rule can be used. Consider the smallest loop of the circuit, containing both the \(1\,\mathrm{\Omega}\) resistor and the capacitor. There are only two potential differences involved here, the one across the capacitor \(V_C\) and \(V_2\). Kirchhoff's loop rule tells us these must add to zero, and so \[V_C=V_2=1.5\,\mathrm{V}.\]
Multiplying the voltage by the capacitance gives the accumulated charge on the capacitor:\[Q=1.5\,\mathrm{V}\cdot 5\times10^{-9}\,\mathrm{F}=7.6\,\mathrm{nC}.\]